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Some chemicals are also corrosive to metals. Both acidic \(pH < 4\) and basic/alkaline \(pH > 10\) solutions can cause chemical burns. Many oxidizing agents \(e.g. hydrogen peroxide, chlorine\) and dehydrating agents \(e.g. phosphorous pentoxide, calcium oxide\) can also be corrosive. This is a quick reference guide only, refer to the Chemical SOP for more detailed information. ) /E (Corrosive chemicals are chemicals that can cause immediate and sometimes permanent damage to the skin, eyes, respiratory system, and tissues upon contact. Some chemicals are also corrosive to metals. Both acidic \(pH < 4\) and basic/alkaline \(pH > 10\) solutions can cause chemical burns. Many oxidizing agents \(e.g. hydrogen peroxide, chlorine\) and dehydrating agents \(e.g. phosphorous pentoxide, calcium oxide\) can also be corrosive. This is a quick reference guide only, refer to the Chemical SOP for more detailed information. ) /Pg 7 0 R /K [13] >> endobj 22 0 obj << /Type /StructElem /S /H3 /T (What are the Symptoms of Corrosive Exposure?) /E (What are the Symptoms of Corrosive Exposure?) /Pg 7 0 R /K [14] >> endobj 23 0 obj << /Type /StructElem /S /H4 /T (Exposure to corrosive chemicals can produce a variety of symptoms, depending on the route of exposure. Exposure symptoms include the following:) /E (Exposure to corrosive chemicals can produce a variety of symptoms, depending on the route of exposure. Exposure symptoms include the following:) /Pg 7 0 R /K [15] >> endobj 24 0 obj << /Type /StructElem /S /P /P 73 0 R /ActualText (Eyes: pain, blood shot eyes, tearing, and blurred vision) /Pg 7 0 R /K [16] >> endobj 25 0 obj << /Type /StructElem /S /P /P 74 0 R /ActualText (Skin: redness, pain, inflammation, bleeding, blisters, ulcers, skin discoloration, and burns) /Pg 7 0 R /K [17] >> endobj 26 0 obj << /Type /StructElem /S /P /P 75 0 R /ActualText (Respiratory: burning sensation, coughing, wheezing, laryngitis, shortness of breath, nausea, and vomiting) /Pg 7 0 R /K [18] >> endobj 27 0 obj << /Type /StructElem /S /H3 /T (What are the Classes of Corrosives?) /E (What are the Classes of Corrosives?) /Pg 7 0 R /K [19] >> endobj 28 0 obj << /Type /StructElem /S /H4 /T (The classes of corrosives and examples of those corrosives encounted at 91 are the following:) /E (The classes of corrosives and examples of those corrosives encounted at 91 are the following:) /Pg 7 0 R /K [1] >> endobj 29 0 obj << /Type /StructElem /S /P /P 76 0 R /ActualText (Inorganic Acids) /Pg 7 0 R /K [2] >> endobj 30 0 obj << /Type /StructElem /S /P /P 77 0 R /ActualText (Examples: Hydrochloric acid, Hydrofluoric acid, Phosphoric Acid, Sulfuric acid) /Pg 7 0 R /K [3] >> endobj 31 0 obj << /Type /StructElem /S /P /P 78 0 R /ActualText (Inorganic Bases) /Pg 7 0 R /K [4] >> endobj 32 0 obj << /Type /StructElem /S /P /P 79 0 R /ActualText (Examples: Ammonium hydroxide, Potassium hydroxide, Sodium hydroxide) /Pg 7 0 R /K [5] >> endobj 33 0 obj << /Type /StructElem /S /P /P 80 0 R /ActualText (Organic Acids) /Pg 7 0 R /K [6] >> endobj 34 0 obj << /Type /StructElem /S /P /P 81 0 R /ActualText (Examples: Acetic acid, Formic acid, Trichloroacetic acid ) /Pg 7 0 R /K [7] >> endobj 35 0 obj << /Type /StructElem /S /P /P 82 0 R /ActualText (Organic Bases) /Pg 7 0 R /K [8] >> endobj 36 0 obj << /Type /StructElem /S /P /P 83 0 R /ActualText (Examples: Hydroxylamine, Tetramethylethylenediamine \(TEMED\), Triethylamine ) /Pg 7 0 R /K [9] >> endobj 37 0 obj << /Type /StructElem /S /P /P 84 0 R /ActualText (Oxidizing Acids) /Pg 7 0 R /K [10] >> endobj 38 0 obj << /Type /StructElem /S /P /P 85 0 R /ActualText (Examples: Chromic acid, Nitric acid, Perchloric acid ) /Pg 7 0 R /K [11] >> endobj 39 0 obj << /Type /StructElem /S /H3 /T (Safety Precautions for Working with Corrosives ) /E (Safety Precautions for Working with Corrosives ) /Pg 7 0 R /K [20] >> endobj 40 0 obj << /Type /StructElem /S /P /P 86 0 R /ActualText (Work with corrosive chemicals in a well-functioning chemical fume hood, glovebox, or other local source of ventilation. ) /Pg 7 0 R /K [21] >> endobj 41 0 obj << /Type /StructElem /S /P /P 87 0 R /ActualText (Always work within 10 seconds of a fully functional eyewash station and safety shower.) /Pg 7 0 R /K [22] >> endobj 42 0 obj << /Type /StructElem /S /P /P 88 0 R /ActualText (Keep corrosive chemical containers closed when not in use. ) /Pg 7 0 R /K [23] >> endobj 43 0 obj << /Type /StructElem /S /P /P 89 0 R /ActualText (To prevent splattering, add acid in small quantities to water. ) /Pg 7 0 R /K [24] >> endobj 44 0 obj << /Type /StructElem /S /P /P 90 0 R /ActualText (Never add water to acid. ) /Pg 7 0 R /K [25] >> endobj 45 0 obj << /Type /StructElem /S /P /P 91 0 R /ActualText (When working with corrosives, wear safety goggles, chemically appropriate gloves, lab coats, and long pants. A chemical-resistant apron should also be considered when working with large amounts of concentrated acids. ) /Pg 7 0 R /K [26] >> endobj 46 0 obj << /Type /StructElem /S /P /P 92 0 R /ActualText (Calcium gluconate gel must be kept on hand in case of an emergency when conducting research involving hydrofluoric acid. Before continuing to use hydrofluoric acid in the lab, replace any expired calcium gluconate solutions. ) /Pg 7 0 R /K [27] >> endobj 47 0 obj << /Type /StructElem /S /P /P 93 0 R /ActualText (NOTE: Never use hot or concentrated perchloric acid solutions in a regular fume hood, as perchloric acid fumes will form explosive salts in the fume hood ductwork. Contact the Chemical Hygiene Officer for consultation and approval. ) /Pg 7 0 R /K [28] >> endobj 48 0 obj << /Type /StructElem /S /Figure /P 17 0 R /Pg 7 0 R >> endobj 49 0 obj << /Type /StructElem /S /H3 /T (References) /E (References) /Pg 7 0 R /K [35] >> endobj 50 0 obj << /Type /StructElem /S /P /P 94 0 R /ActualText (91 Chemical Hygiene Plan) /Pg 7 0 R /K [36 37] >> endobj 51 0 obj << /Type /StructElem /S /H2 /T (Need Help?) /E (Need Help?) /Pg 7 0 R /K [29] >> endobj 52 0 obj << /Type /StructElem /S /P /P 95 0 R /ActualText (Ask the lab/shop supervisor) /Pg 7 0 R /K [30] >> endobj 53 0 obj << /Type /StructElem /S /P /P 96 0 R /ActualText (Ask the department/college safety staff) /Pg 7 0 R /K [31] >> endobj 54 0 obj << /Type /StructElem /S /P /P 97 0 R /ActualText (Ask 91 Environmental Health & Safety) /Pg 7 0 R /K [32] >> endobj 55 0 obj << /Type /StructElem /S /P /P 98 0 R /ActualText (Chemical Hygiene Officer: skye.kelty@sjsu.edu; 408-924-1978) /Pg 7 0 R /K [33] >> endobj 56 0 obj << /Type /StructElem /S /P /P 99 0 R /ActualText (Director: ehs@sjsu.edu; 408-924-1969) /Pg 7 0 R /K [34] >> endobj 57 0 obj << /ca 1 /BM /Normal >> endobj 58 0 obj << /CA 1 /ca 1 /LC 0 /LJ 0 /LW 1 /ML 4 /SA true /BM /Normal >> endobj 59 0 obj << /CA 1 /ca 1 /LC 0 /LJ 0 /LW 8 /ML 4 /SA true /BM /Normal >> endobj 60 0 obj << /Length 293 /N 3 /Filter /FlateDecode >> stream x}JԂ(28hiRpi"VSAOHStspu+.c(#ARx@?F[V[G@`*dK$O.K o@6`O,f'˘O asx0A6vf 8{c7%opZ:u Q 0Q٣F *Ԑ(SDGACAajgrx]s PxM cvhO> stream xxU)&*" (EEY~Q(VUYu ]HD Z&3ܛy$3s̙HJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJJGk¤꺪]1 *RjN.%HPs9(a'KǯWN.&nߗO ޔdy1W;LwUSEykIr~u4k)bF@%ٰTjZf+iA)鎚3:Ŀ_;Ͼz[O~6l#tb^\ms>\^5.u(FT۸I%xC&inD;ܜ~Ep|Vnnc%WˈܜN}rúuRRvnnvYш 'n@Pas㖡ٹYCh'0Pon՞C?%T3٩99Y2)/9O<;bDNNnz^֍dh'=ĤDMz/ڻリ6LOF%*^\[Jsx}ZgyXhmܺͧǿr 5,{NLeDbW {'uY+Pq ]>}_pQڤ΁#E!NZ6otS9u,=-+B c;g徂.!Fo`](rQ o 8TZ\ބu~.CKQλ6#ѨaF4oB-5ǫ**5iE#<zmTxhg[Ofj|jlNOH'+TsΝ;؅V4wQmn~,5^mK* l ,=BIB5kT~rL8 XZV(4TBQ >!A<˲v D0y E>Y=ĤQ# cV~$;e^.*_7ѨiYecF n7k//.9hF6ڊoZf% 9inݦ+FS h 6UZMIЫ@wm&Va U@=ǰ^c"ɈDMwߤ+0PȽE! )Aze֭۴9A4BYS^U Tz Ywc@_R=:Y%R_,bt -VDb@tBPL[@L]JG1DeSiG ]kG;Ub_Gi[΃Uذ%4aR6Q+Y1By/[94|ڴ0gt=XzIZISŇp<:gC +oGҩ)`ڬ T˂^Qf[_\ᣳy#+jt>C0Ģk Tܸv Ou;v܃GG(D,~>jݦCQ}0m8')˅y /~:\S3*:eti"vcSJ@|tjt-p'"WQ^wIٶ-a{-EAFy4s=]J?KhNlyk;q<}!'Tz($j &6@ІNԻ6) ѩ,f:rkJ)sqJnIջY>$ʁ;׼ũ쏇¤)xp,ڷ$1:%:>:x<=iTވ"X,v q$Tz`LB:U2pZC gNl@V( lҩ[$s-(\Q[ ,/ tx1tp뽍[&xtF_t^C&S[ ?F]/tjR$V}bQ)tt`VhRw#m«&_c;uʅ.gbQ"$:&']5>&.9Rt۩:1٫KBѷ}ʳ;hFɎ-5Ni*פ:⽽ݬ0,Zтsײ;{܋ <ܗѩRh"?F]I%r|~~$t>l@ rm)KJ*=-+9h64v;\t>Kux震J7X*Mq$w*tt> <&y#8.$j'Nf#|Fnݺu2x[ )~8mn??hv4 !_D'2Tk=:U~'*:=02h#?[S Kw+j;15[EߌX5N] :5nX(i%jNx=p#ҙ{b1-.bFbX%&f)?N>n͖yF5+g0+ t&pѩP@?tqJ1o#ݥt: l(S.QXa=U yScM%J'y EөRR㵨Z.$Q 4y*}їRcCCΦe0dz9|:]Jkp1+Pm:4=L1G;j}9k}NMkI !V8mY_ :5d k-jkYTpeȳ IAYƦ};~Ѽg:S E-3?MF0 NuzyVI 13)Qx2 0GB3\n1֤B&JTIY҈2۔y[j;2OގwNu)Tps:.dbߏs*$U,Wg2Ok'1K;ҩI2wN:u7" Ug*aӁ f;#yWTJ5Yⶋ9[װ$-|Ψc*/BkPBajt5HS2G@;7 tp3^鎩S>k92dF)*b4vؐH|TZr'kGKrv6y55nYJ]puG oe!ۀ=g U_l%\O-w ?hPwB5R!j' D[PJic ss9XvDJ[v&:Бo!ӗ:L,uud%`i;J%?p}Aҟ^Wzs")z'л-a=eNjъf7[] VϿ/aAJ<>-`Ė LJ'U((PbvUt:[4_^/FQmU{E FtcԎge;8*XѩR>>Y? 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